Om jag tolkar Sheldon rätt så säger han att bokstaven står för däcksbredd.
French sizes:
In the French system, the first number is the nominal diameter in mm, followed by a letter code for the width: "A" is narrow, "D" is wide. The letter codes no longer correspond to the tire width, since narrow tires are often made for rim sizes that originally took wide tires; for example, 700 C was originally a wide size, but now is available in very narrow widths, with actual diameters as small as 660 mm.